Electronic absorption spectra and the structure of the ligand in metal complexes with purpurin

Authors: Fain, V.; Zaitsev, B.; Ryabov, M.

Source: Russian Journal of Coordination Chemistry, Volume 31, Number 3, March 2005 , pp. 221-224(4)

Publisher: MAIK Nauka/Interperiodica

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Abstract:

Purpurin complexes with metals are formed due to metal coordination at the peri- or ortho-hydroxycarbonyl group involving anthraquinoid tautomers. The l,* bands of metal purpurinates correspond to 1,10- and 1,4-anthraquinoid anions, 9,10-anthraquinoid structures are not typical of them.

Document Type: Research Article

DOI: http://dx.doi.org/10.1007/s11173-005-0080-8

Affiliations: Peoples Friendship University, ul. Miklukho-Maklaya 6, 117198, Moscow, Russia,

Publication date: March 1, 2005

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