@article {Bezrukavnikova:2002:1070-3284:212,
	author = "Bezrukavnikova I.M. and Polynova T.N. and Poznyak A.L. and Stopolyanskaya L.V.",
	title = "Ethylenediamine-N,N"-Diacetate Ion (Edda2-) as a Tridentate Ligand: Synthesis and Structure of the Co(Edda)(Dien)ClO4 H2O and Co(Edda)(En)(CN) 2H2O Complexes",
	journal = "Russian Journal of Coordination Chemistry",
	volume = "28",
	number = "3",
	year = "2002",
	abstract = "<P>The cobalt(III) complexes with tridentate ethylenediamine-N,N&quot;-diacetate ions (Edda^2&ndash;) and additional ligands, namely, diethylenetriamine (Dien) or ethylenediamine (En) and cyanide ions, were synthesized. As follows from X-ray diffraction analysis of [Co(Edda)(Dien)]ClO_4 &#183; H_2O (monoclinic crystals with a = 9.243 (2) &Aring;, b = 14.167 (4) &Aring;, c = 13.046 (3) &Aring;, <IMG SRC="/iso-ents/isogrk32/beta-s.gif" ALT="beta"> = 91.19 (2)&#176;, Z = 4, space group P2_1/c), the secondary N atom of the Dien ligand occupies the trans-position relative to the N atom of the Edda^2&ndash; ligand, which contains a free acetate group. Two fac-isomers of [Co(Edda)(En)(CN)] with the CN^&ndash; ion in the cis- and trans-positions relative to the oxygen atom of the carboxyl group were isolated, and the structure of the trans-(O,CN)-[Co(Edda)(En)(CN)]_ &#183; 2H_2O was determined: monoclinic crystals with a = 9.136 (3) &Aring;, b = 15.484 (3) &Aring;, c = 10.564 (3) &Aring;, <IMG SRC="/iso-ents/isogrk32/beta-s.gif" ALT="beta"> = 110.67 (5)&#176;, Z = 4, space group P2_1/c.</P>",
	pages = "212-216",
	url = "http://www.ingentaconnect.com/content/maik/ruco/2002/00000028/00000003/00372763"
}