Exchange Processes in Pb(II) Complexes

Authors: Chernysh Y.E.; Borodkin G.S.; Korobov M.S.; Luk'yanov B.S.; Stankevich N.V.; Borodkina I.G.; Vdovichenko V.Y.; Korobov Y.M.

Source: Russian Journal of Coordination Chemistry, Volume 28, Number 3, March 2002 , pp. 170-174(5)

Publisher: MAIK Nauka/Interperiodica

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Abstract:

A novel technique of 2D exchange NMR with suppression of the coherent magnetization transfer is suggested for the collection of useful chemical information on the basis of standard 2D exchange spectroscopy. In this technique, only one nucleus of the coupled spin system involved in chemical exchange is excited (so-called multiplet selectivity or semiselective excitation). In this case, the multiplet structure of the selectively irradiated nucleus behaves as an uncoupled multisite system.

Language: English

Document Type: Regular paper

Affiliations: 1: Institute of Physical and Organic Chemistry, Rostov State University, pr. Stachki 194/3, Rostov-on-Don, 344104 Russia

Publication date: 2002-03-01