Standard reference exergies of chemical elements in the oceanic reference medium. II. Estimation of the equilibrium of ecospecies in the oceanic medium

Author: Pinaev, G.1

Source: Journal of Engineering Physics and Thermophysics, Volume 79, Number 5, September 2006 , pp. 1039-1049(11)

Publisher: Springer

Abstract:

A refined system (set), as compared to the Ocean-1 and Ocean-2 systems, of equilibrium standard reference exergies of chemical elements, called the Ocean-3 system, has been developed. The exergies forming the Ocean-3 system were calculated with account for the large oceanic ionic-ligand equilibrium between all chemical elements present in the oceanic medium involving about 300 reactions of complexation of elements. The independence of the equilibrium standard reference exergy of an element of its representative ecospecies was substantiated theoretically and supported by a concrete calculation.

Document Type: Research article

DOI: 10.1007/s10891-006-0201-3

Affiliations: 1: Email: pinaev2004@mail.ru

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