If you are experiencing problems downloading PDF or HTML fulltext, our helpdesk recommend clearing your browser cache and trying again. If you need help in clearing your cache, please click here . Still need help? Email help@ingentaconnect.com

Ultrasound devulcanization of unfilled natural rubber networks, studied via component molecular mobility

The full text article is not available for purchase.

The publisher only permits individual articles to be downloaded by subscribers.

Abstract:

13C NMR solids spectroscopy and transverse relaxation, and 1H relaxation and pulsed‐gradient spin‐echo self‐diffusion measurements at 70 °C were used to study molecular and segmental mobilities in natural rubber before and after sulfur crosslinking, and after subsequent devulcanization using intense ultrasound. NMR relaxation does not clearly distinguish between entangled and crosslinked network mobility, but unentangled sol and oligomeric species are separable within the longer T2 decay components. Ultrasound reactor settings affect the amount of extractable sol generated. Some two‐thirds of the sol is entangled, with number‐average molecular weights (Mn) above 10 000 g mol−1. Samples also contain near 2 wt% of inert light species (Mn < 400 g mol−1); ultrasound is relatively ineffective in producing additional oligomeric material. All proton mobilities increase as more sol is produced, but 13C relaxation, reflecting intramolecular effects, indicates a slight decrease in backbone mobility. In contrast with other rubbers, in natural rubber, neither the glass transition nor the sol diffusion rate is greatly affected by the extent of ultrasound exposure. Comparisons with previous similar work of this laboratory, particularly styrene‐butadiene rubber, are useful in confirming the molecular mechanisms involved. Copyright © 2007 Society of Chemical Industry

Keywords: NMR relaxation; devulcanization; diffusion; natural rubber; sol; ultrasound

Document Type: Research Article

DOI: http://dx.doi.org/10.1002/pi.2216

Publication date: July 1, 2007

More about this publication?
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more