Free Content On the differences between bubble-mediated air-water transfer in freshwater and seawater

 Download
(PDF 1,910.4 kb)
 
Download Article:

Abstract:

Bubble populations and gas transfer velocities were measured in cleaned and surfactant-influenced freshwater and seawater. A nonlinear fitting technique was used to partition the total gas transfer velocity for a gas in each water type into a turbulence- and bubble-mediated fraction. This showed that the bubble-mediated transfer fraction was larger in cleaned freshwater than in cleaned seawater and that the difference was a function of diffusivity and solubility. This was explained by the fact that the bubble measurements showed that bubble plumes in cleaned freshwater had a higher concentration of large bubbles and a lower concentration of small bubbles than the plumes in cleaned seawater. The differences between the behavior of the bubble-mediated gas flux in cleaned freshwater and cleaned seawater show that caution should be used when intercomparing laboratory results from measurements made in different media. These differences also will make parameterizations of bubble-mediated gas exchange developed using freshwater laboratory data difficult to apply directly to oceanic conditions. It was found that adding a surfactant to seawater had minimal impact on the concentration of bubbles in the plumes. Because surfactants decrease the gas flux to the individual bubbles, the similarity in bubble population meant that the addition of surfactant to seawater decreased the bubble-mediated gas flux compared to the flux in cleaned seawater. In contrast, the addition of a surfactant to freshwater increased the concentration of bubbles by over an order of magnitude. This increase in bubble population was large enough to offset the decrease in the flux to the individual bubbles so that the net bubble-mediated gas flux in freshwater increased when surfactant was added. This difference in behavior of the bubble population and bubble-mediated transfer velocity between surfactant-influenced and cleaned waters further complicates interrelating laboratory measurements and applying laboratory results to the ocean.

Document Type: Research Article

DOI: http://dx.doi.org/10.1357/0022240973224210

Publication date: September 1, 1997

More about this publication?
  • The Journal of Marine Research publishes peer-reviewed research articles covering a broad array of topics in physical, biological and chemical oceanography. Articles that deal with processes, as well as those that report significant observations, are welcome. In the area of biology, studies involving coupling between ecological and physical processes are preferred over those that report systematics. Authors benefit from thorough reviews of their manuscripts, where an attempt is made to maximize clarity. The time between submission and publication is kept to a minimum; there is no page charge.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • ingentaconnect is not responsible for the content or availability of external websites
Related content

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more