If you are experiencing problems downloading PDF or HTML fulltext, our helpdesk recommend clearing your browser cache and trying again. If you need help in clearing your cache, please click here . Still need help? Email help@ingentaconnect.com

Crystal Structure of Methyl Orange Derivatives and Their Electronic Spectra

$25.00 plus tax (Refund Policy)

Buy Article:

Abstract:

Azo dyes and pigments are widely used in the imaging industry because of their versatile colors as well as their low price. However, it is often pointed out that the color in the solid state is sometimes drastically different from that in solution. An attempt has been therefore made in the present investigation to elucidate the electronic structure of two classical simple azo dyes on the basis of the crystal structure: methyl orange [Na(I)-(dimethylamino)azobenzene-4-sulfonate (MO)] and its derivative [4-(dimethylamino)azobenzene-sulfonic acid (MOH)]. Accordingly the authors found a new trinuclear Na complex (pale red) of MO, as well as a new polymorph (purple) of MOH in addition to the previously reported phase (vivid red). In MO and also in the purple phase of MOH, excitonic interactions are basically responsible for the color change on going from solution to the solid state. On the other hand, the authors found a zwitterionic structure in the vivid-red phase of MOH as formed by NH···O intermolecular hydrogen bonds. The vivid-red color can be interpreted as arising mainly from the zwitterionic structure.

Document Type: Research Article

DOI: http://dx.doi.org/10.2352/J.ImagingSci.Technol.2009.53.5.050302

Affiliations: Graduate School of Engineering, Yokohama National University, 240-8501 Yokohama, Japan

Publication date: September 1, 2009

More about this publication?
  • The Journal of Imaging Science and Technology (JIST) is dedicated to the advancement of imaging science knowledge, the practical applications of such knowledge, and how imaging science relates to other fields of study. The pages of this journal are open to reports of new theoretical or experimental results, and to comprehensive reviews. Only original manuscripts that have not been previously published, nor currently submitted for publication elsewhere, should be submitted.
  • Editorial Board
  • Information for Authors
  • Subscribe to this Title
  • Membership Information
  • Information for Advertisers
  • Terms & Conditions
  • Privacy Policy
  • ingentaconnect is not responsible for the content or availability of external websites
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more