IngentaConnect Atomic and electronic structure of Mo6S9-xIx nanowires

Authors: Meden, A.; Kodre, A.; Gomilsek, J Padeznik; Arcon, I.; Vilfan, I.; Vrbanic, D.; Mrzel, A.; Mihailovic, D.

Source: Nanotechnology, Volume 16, Number 9, September 2005 , pp. 1578-1583(6)

Publisher: Institute of Physics Publishing

Abstract:

Moybdenum-based subnanometre diameter nanowires are easy to synthesize and disperse, and they exhibit a variety of functional properties in which they are superior to other one-dimensional materials. However, further progress in the understanding of physical properties and the development of new and specific applications have so far been impeded by the fact that their structure was not accurately known. Here we report on a combination of systematic x-ray diffraction and extended x-ray absorption fine structure experiments, and first-principles theoretical structure calculations, which are used to determine the atomic skeletal structure of individual Mo₆S_9-xI_x (MoSI_x) nanowires, their packing arrangement within bundles and their electronic band structure. From this work we conclude that the variations in functional properties appear to arise from different stoichiometry, not skeletal structure. A supplementary data file is available from http://stacks.iop.org/0957-4484/16/1578

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