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A new synthesis, including asymmetric synthesis, of spiro[4.n]alkenones from three components: cyclic ketones, chloromethyl p-tolyl sulfoxide, and acetonitrile; and a formal total synthesis of racemic acorone

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Keywords: acorone; asymmetric synthesis; chiral sulfoxide; spiro[4.n]alkenone; spirocycle

Document Type: Research Article

DOI: http://dx.doi.org/10.1016/j.tet.2003.09.099

Affiliations: Department of Chemistry, Faculty of Science, Tokyo University of Science; Kagurazaka, Shinjuku-ku, 162-8601, Tokyo, Japan

Publication date: November 24, 2003

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