Remote substituent effect favoring the formation of syn-adducts in the chelation controlled radical reactions of gamma-benzyloxy-alpha-methylenecarboxylic acid esters

Authors: Nagano H.; Ohkouchi H.; Yajima T.

Source: Tetrahedron, Volume 59, Number 20, 12 May 2003 , pp. 3649-3663(15)

Publisher: Elsevier

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Keywords: radical reaction; 1,3-asymmetric induction; remote substituent effect; Lewis acid; CONFLEX-PM3

Language: English

Document Type: Research article

DOI: http://dx.doi.org/10.1016/S0040-4020(03)00421-6

Affiliations: 1: Department of Chemistry, Faculty of Science, Ochanomizu University, Otsuka, Bunkyo-ku, 112-8610, Tokyo, Japan

Publication date: 2003-05-12

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