Cross-coupling of nonstabilized aziridinylmagnesiums with alkylhalides catalyzed by Cu(I) iodide: a new synthesis of amines bearing a quaternary chiral center and an asymmetric synthesis of both enantiomers of the amines from one chiral starting material

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Keywords: asymmetric synthesis of amines; aziridinylmagnesium; cross-coupling; quaternary chiral center; sulfoxide-magnesium exchange

Document Type: Research Article


Affiliations: Department of Chemistry, Faculty of Science, Science University of Tokyo, Kagurazaka, Shinjuku-ku, 162-8601, Tokyo, Japan

Publication date: April 30, 2001

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