Analysis of the enantioselectivities and initial rates of the hydrosilylation of acetophenone catalyzed by [Rh(cod)Cl]₂/(chiral diphosphine). The quantitative analysis of ligand effects

Authors: Reyes C.; Prock A.; Giering W.P.

Source: Journal of Organometallic Chemistry, Volume 671, Number 1, 1 April 2003 , pp. 13-26(14)

Publisher: Elsevier

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Keywords: Asymmetric catalysis; Ketone; Hydrosilylation; Kinetics; Ligand effects; Quantitative analysis of ligand effects

Language: English

Document Type: Research article

DOI: http://dx.doi.org/10.1016/S0022-328X(02)02221-0

Affiliations: 1: Department of Chemistry, Metcalf Science and Engineering Center, Boston University, 02215, Boston, MA, USA

Publication date: 2003-04-01

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Analysis of the enantioselectivities and initial rates of the hydrosilylation of acetophenone catalyzed by [Rh(cod)Cl]2/(chiral diphosphine). The quantitative analysis of ligand effects