Skip to main content

Local Order of the Transition Metals for the Substitution (Co1 ­ yCuy)2AL(OH)6CL· nH2O (0 y 1) in a Copper-aluminum-layered Double Hydroxide-like Phase

Buy Article:

$28.00 plus tax (Refund Policy)

- The substitution in layered double hydroxide-like phases (LDH) of composition (Co2+1-y Cu2+y)2Al3+(OH)6Cl ­· n H2O (0 y 1) was studied by X-ray diffraction and X-ray absorption spectroscopy. It was found that the lamellar character is maintained over the entire range of the substitution. The local order for the composition {Co2Al} is typical of brucite-like sheets, whereas segregation into small domains may explain the results obtained when the percentage of Cu atoms is increased. The {Cu2Al} end-member material presents a local order around the Cu atoms closely related to the botallackite structure as present in basic layered Cu salts, with the presence of two distinct Cu ­Cu distances.
No Reference information available - sign in for access.
No Citation information available - sign in for access.
No Supplementary Data.
No Data/Media
No Metrics


Document Type: Research Article

Publication date: 2002-04-01

More about this publication?
  • The JOURNAL publishes articles of interest to the international community of clay scientists, including but not limited to areas in mineralogy, crystallography, geology, geochemistry, sedimentology, soil science, agronomy, physical chemistry, colloid chemistry, ceramics, petroleum engineering, foundry engineering, and soil mechanics. Clays and Clay Minerals exists to disseminate to its worldwide readership the most recent developments in all of these aspects of clay materials. Manuscripts are welcome from all countries.

    Clays and Clay Minerals is the official publication of The Clay Minerals Society.

    The Editor-in-Chief is Professor Joseph W. Stucki

    Publications of The Clay Minerals Society
    Source Clays

  • Editorial Board
  • Information for Authors
  • Membership Information
  • Annual Meeting of The Clay Minerals Society
  • Ingenta Connect is not responsible for the content or availability of external websites
  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more