The Nature of Soil Kaolins from Indonesia and Western Australia

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Abstract:

Purified soil kaolins from Indonesia and Western Australia were characterized using analytical TEM, XRD, TGA and chemical analysis. The Indonesian kaolins, formed from tuff, consist of a mixture of tubular kaolin crystals with relatively low Fe concentrations and platy kaolin crystals with higher Fe concentrations. Western Australian kaolins also contained tubular and platy crystals but showed no systematic relationship of crystal morphology with Fe content. The coherently scattering domain (CSD) size of the Indonesian samples (5 ­6 nm for 001, i.e. c axis dimension) is remarkably consistent and is approximately half of the value for the Western Australian kaolins (9.7 ­13.4 nm), and both are much smaller sizes than values for the reference kaolins (15.6 ­27.8 nm). Coherently scattering domain sizes derived from the Scherrer equation are approximately twice the values obtained from the Bertaut-WarrenAverbach Fourier method but the results show the same pattern of variation. For the Indonesian, Western Australian and reference kaolins, the N2-BET surface area ranges 59 ­88, 44 ­56 and 5 ­28 m2/g; the dehydroxylation temperatures range 486 ­499, 484 ­496 and 520 ­544°C, the mean cation exchange capacities (CEC) are 9.4, 5.0 and 3.5 meq 100 g ­1 and the surface densities of charge range 0.10 ­0.14, 0.08 ­0.10 and 0.04 ­0.12 C/m2. The properties of the Western Australian kaolins and Indonesian kaolins differ substantially, but kaolins within each group have similar properties. These results suggest that soil kaolin properties may be characteristic of a particular pedoenvironment and that a systematic study of kaolins in different pedoenvironments is required.

Keywords: -ANALYTICAL TEM; SOIL KAOLIN; XRD.

Document Type: Research Article

DOI: http://dx.doi.org/10.1346/000986002760832793

Publication date: April 1, 2002

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  • The JOURNAL publishes articles of interest to the international community of clay scientists, including but not limited to areas in mineralogy, crystallography, geology, geochemistry, sedimentology, soil science, agronomy, physical chemistry, colloid chemistry, ceramics, petroleum engineering, foundry engineering, and soil mechanics. Clays and Clay Minerals exists to disseminate to its worldwide readership the most recent developments in all of these aspects of clay materials. Manuscripts are welcome from all countries.

    Clays and Clay Minerals is the official publication of The Clay Minerals Society.

    The Editor-in-Chief is Professor Joseph W. Stucki jstucki@illinois.edu

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