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Open Access Preparation and Luminescence Properties of Orange-red Phosphors Ca3Y2 (Si3O9)2:Eu3+

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A series of orange-red phosphors Ca3Y2-2x(Si3O9)2:2xEu3+ were synthesized by a conventional solid-state reaction. Their photoluminescence properties were investigated by X-ray diffraction. The results show that the prepared Ca3Y2(Si3O9)2:Eu3+ crystals are Ca3Y2 (Si3O9)2 phase. There are two excitation bands, namely, the O2-−Eu3+ intensive charge transition band (CTB) and the weak f − f transition absorption of Eu3+ in the excitation spectra. The main emissions are located at 587 and 610 nm under the excitation of 225 nm, respectively, corresponding to 5D07F1 and 5D07F2 transition, and the intensity of the former is similar to that of the latter. However, the intensive emission is located at 615 nm and the weak emission is located at 591 nm under the excitation of 392 nm. The decay time of 5D0 level in Eu3+ was determined via the time resolved spectra. The effect of Eu3+ content on the emission spectra intensity of Ca3Y2(Si3O9)2:Eu3+ was investigated. The luminescent intensity increases with increasing Eu3+ content. The concentration quenching does not occur.
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Keywords: europium-doped; luminescent property; orange-red; phosphors; yttrium calcium silicate

Document Type: Research Article

Affiliations: College of Physics Science and Technology, Hebei University, Baoding 071002, Hebei, China

Publication date: 2013-12-01

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  • Journal of the Chinese Ceramic Society (JCCS), published in Chinese and in English, is a comprehensive monthly periodical focused on the fields of inorganic and non-metallic materials. The main purpose of the JCCS is to report the latest creative achievements in research, production and design for ceramics, glass, cementing materials, refractory, artificial crystals and other non-metallic materials. JCCS is regarded as an important journal in inorganic and non-metallic materials sciences in China and has been awarded by China Association for Science and Technology. The full-text of papers in JCCS is also published by CNKI (China National Knowledge Infrastructure). JCCS is indexed in EI Compendex, CA( Chemical Abstracts) ,SA and Ж and more than 20 databases.
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