Open Access Effect of Calcination Temperature on Morphology and Properties of White Long-lasting Phosphor Y2O2S:Tb3+, Sr2+, Zr4+

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Abstract:

The white-light long-lasting phosphor of Y2O2S:Tb3+, Sr2+, Zr4+ was prepared by a solid state reaction method. The effect of calcination temperature on the phase, surface morphology and luminescent properties of the samples was investigated. The samples were characterized by X-ray diffractometer, scanning electron microscope, fluorescence spectrophotometer, illuminometer and thermally stimulated spectrometer, respectively. The results show that the samples are composed of Y2O2S and Y2O3 phases, in which Y2O3 is a major phase at the calcination temperature of 950 . The pure Y2O2S phase was obtained at 1 000 and 1 050 . Y2O3 phase appeared at > 1 050 . The position and shape of Tb3+ emission peaks under the 288 nm excitation appeared similar for all the samples. The blue light emission at 417 nm and the yellowish-green light emission at 544 nm originated from the 5D37F5 and the 5D47F5 transitions of Tb3+, respectively. The trap depth was 0.64 eV and the decay time was 160 s (≥1 mcd/m2) for the sample synthesized at 1 000 .

Keywords: rare earths; solid state reaction method; white-light long-lasting phosphor; yttrium oxysulfide

Document Type: Research Article

DOI: http://dx.doi.org/10.7521/j.issn.0454–5648.2013.06.10

Affiliations: College of Physics and Optoelectronics, Taiyuan University of Technology, Taiyuan 030024, China

Publication date: June 1, 2013

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  • Journal of the Chinese Ceramic Society (JCCS), published in Chinese and in English, is a comprehensive monthly periodical focused on the fields of inorganic and non-metallic materials. The main purpose of the JCCS is to report the latest creative achievements in research, production and design for ceramics, glass, cementing materials, refractory, artificial crystals and other non-metallic materials. JCCS is regarded as an important journal in inorganic and non-metallic materials sciences in China and has been awarded by China Association for Science and Technology. The full-text of papers in JCCS is also published by CNKI (China National Knowledge Infrastructure). JCCS is indexed in EI Compendex, CA( Chemical Abstracts) ,SA and Ж and more than 20 databases.
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