Mechanical Properties and Crystallization Behavior of GeS2Sb2S3In2S3 Chalcogenide Glass

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Abstract:

54GeS2–36Sb2S3–10In2S3 glass‐ceramics were prepared by heat‐treating the base glass above Tg for different durations. The results of Raman spectra and XRD patterns show that the first precipitated crystals during the heat treatment are In2S3 and the crystallization of the Sb2S3 and GeS2 subsequently occurs. Bulk samples heat‐treated at 295°C for different heating rates and durations are used to study the crystallization mechanism and evolution of the three crystallization peaks (CPs). It is found that three CPs partly overlap with each other and then separate with increasing heat‐treating durations.

Document Type: Research Article

DOI: http://dx.doi.org/10.1111/j.1551-2916.2012.05117.x

Publication date: April 1, 2012

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