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Oxidation of Zirconium Diboride with Tungsten Carbide Additions

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Abstract:

The oxidation resistance of zirconium diboride (ZrB2) ceramics with tungsten carbide (WC) additions was studied. ZrB2 ceramics, nominally pure and with WC additions of 4, 5, and 6 mol%, were densified by pressureless sintering. During heating, the WC that was added to the ceramic dissolved into the ZrB2 matrix, forming a solid solution. Oxidation behavior was evaluated using isothermal furnace oxidation at 1500°C and 1600°C. The presence of tungsten reduced both the weight gain and oxide scale thickness compared with nominally pure ZrB2. After oxidation at 1600°C for 3 h, the thickness of the ZrO2 outer scale was reduced from 4.7 mm for nominally pure ZrB2 to 0.5 mm for the ceramic containing 6 mol% WC. Analysis showed that WC additions improved the oxidation resistance of ZrB2 by changing the morphology of the zirconia scale formed during oxidation.

Document Type: Research Article

DOI: http://dx.doi.org/10.1111/j.1551-2916.2010.04216.x

Affiliations: Department of Materials Science and Engineering, Missouri University of Science and Technology, Rolla, Missouri 65409

Publication date: April 1, 2011

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