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Photoluminescence of Mn2+ Centers in Chalcohalide Glasses

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We report on photoluminescence from Mn2+-doped chalcohalide glasses of the GeS2–Ga2S3–CsCl system. Upon blue excitation at 447 nm, a broad emission band occurs in the green spectral range from 500 to 600 nm, indicating the presence of tetrahedrally coordinated Mn2+ species. When the Mn2+-concentration is increased up to 2 mol%, an increasingly intense secondary emission band evolves at about 610–660 nm. Meanwhile, the intensity of the green band decreases gradually and shifts toward the red, resulting a very flatten luminescence from 500 to 750 nm, which provides a promising white light emitting source. As for the origin of this unique luminescence behavior of Mn2+, it is proposed that the ligand coordination number of Mn2+ in the present chalcohalide glasses experiences a partial change from tetrahedral to octahedral coordination.

Document Type: Research Article


Affiliations: 1: Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China 2: Department of Materials Science, University of Erlangen-Nuremberg, Erlangen 91058, Germany

Publication date: March 1, 2011

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