Skip to main content

Growth and Mechanism of Network-Like Branched Si3N4 Nanostructures

Buy Article:

$51.00 plus tax (Refund Policy)


The high-yield synthesis of network-like branched silicon nitride (Si3N4) nanostructures by a simple template catalyst-assisted pyrolysis of a polymer precursor, perhydropolysilazane, was reported. The templates were silicon wafers deposited with Fe films of 5–20 nm in thickness. The processes simply involved thermal cross-linking of the preceramic polymer, crushing of the solidified polymer chunks into fine powder, and thermal pyrolysis of the powder under flowing high-purity nitrogen. The collected white network-like branched nanostructures are α-Si3N4 of hexagonal phase, and their microstructures, in which the diameters of each linear part of the network-like nanostructure varied in a very wide range from tens of nanometers to hundreds of nanometers, strongly depend on the applied growth parameters, where the key factors are the heating rate and catalyst thickness for change in the diameters. It was proposed that the Si3N4 nanonetworks were formed through “metal-absorption on the surface of nanostructures” model by vapor–liquid–solid mechanism. The reaction mechanism of Si3N4 nanonetworks was also discussed.

Document Type: Research Article


Affiliations: 1: School of Engineering and Technology, China University of Geosciences at Beijing, Beijing 100083, China 2: Faculty of Science, Beijing University of Posts and Telecommunications, Beijing 100876, China 3: State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University, Beijing 100084, China

Publication date: August 1, 2010


Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more