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Effect of Sc Substitution for Al on the Optical Properties of Transparent Ce:YSAG Ceramics

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Abstract:

Transparent Ce:YAG (Ce:Y3Al5O12) and Ce:YSAG (Ce:Y3ScxAl5−xO12) ceramics have been successfully fabricated using Sc3+ to substitute for Al3+ in Ce:YAG. The effect of Sc substitution on the luminescent properties of Ce:YAG has been investigated. At the substitution level of 20 at.% of Sc3+ for Al3+, the emission intensity of Ce:YSAG is the highest. Meanwhile, the doping of Sc into Ce:YAG lattice broadened both the absorption and emission bands, which is believed to be due to the inhomogeneous broadening of the 5d energy level of Ce3+ caused by the Sc3+ substitution.

Document Type: Research Article

DOI: https://doi.org/10.1111/j.1551-2916.2008.02429.x

Affiliations: Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Publication date: 2008-07-01

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