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Effect of CuO on the Sintering Temperature and Piezoelectric Properties of (Na0.5K0.5)NbO3 Lead-Free Piezoelectric Ceramics

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Abstract:

When a small amount of CuO was added to (Na0.5K0.5)NbO3 (NKN) ceramics sintered at 960°C for 2 h, a dense microstructure with increased grains was developed, probably due to liquid-phase sintering. The Curie temperature slightly increased when CuO exceeded 1.5 mol%. The Cu2+ ion was considered to have replaced the Nb5+ ion and acted as a hardener, which increased the Ec and Qm values of the NKN ceramics. High piezoelectric properties of kp=0.37, Qm=844, and 3T/0=229 were obtained from the specimen containing 1.5 mol% of CuO sintered at 960°C for 2 h.

Document Type: Research Article

DOI: https://doi.org/10.1111/j.1551-2916.2008.02408.x

Affiliations: 1: Department of Materials Science and Engineering, Korea University, Seoul 136-701, Korea 2: Korea Electronics Technology Institute, Gyeonggi-Do 463-816, Korea

Publication date: 2008-07-01

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