Effect of Electrode Microstructure on the Sensitivity and Response Time of Potentiometric NOX Sensors
Authors: White, Briggs; Chatterjee, Suman; Macam, Eric; Wachsman, Eric
Source: Journal of the American Ceramic Society, Volume 91, Number 6, June 2008 , pp. 2024-2031(8)
Abstract:Nanometric La2CuO4 was synthesized with the Pechini method, co-precipitation, and two variations of the auto-ignition technique for fabricating NOX sensor electrodes. The auto-ignition technique produced the most phase-pure powder with the smallest particle size and the largest specific surface area. The sensor electrodes were subjected to various thermal treatments resulting in a variety of electrode grain sizes and distributions. The response times of the sensors were exponentially dependent on electrode grain size. Sensors with fine-grained electrodes were able to produce a steady-state and consistent voltage at lower temperatures; improving their response sensitivity. Sensors fabricated with powders synthesized through the auto-ignition route responded quickly, sensitively, and reproducibility to NO.
Document Type: Research Article
Affiliations: Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611
Publication date: June 1, 2008