Chemistry and Structure of Anion-Deficient Perovskites with Translational Interfaces

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A general description and review is given of a new type of anion-deficient perovskite-based structure where the perovskite parent structure is fragmented by periodically spaced translational interfaces. These interfaces demonstrate properties similar to those of the crystallographic shear (CS) planes in the ReO3-type oxides and can be considered to be CS planes in the perovskite framework that contains cations at the A positions. The building principles and chemical compositions of such CS structures will be discussed.

Document Type: Research Article


Affiliations: 1: Department of Chemistry, Moscow State University, Moscow 119991, Russia 2: EMAT, University of Antwerp, B-2020 Antwerp, Belgium

Publication date: June 1, 2008

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