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Phase Equilibrium Investigations on Na–K–(+″)-Alumina

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The activities of Na2O and K2O dissolved in mixed-alkali Na–K–(+″)-Al2O3 (NKBA) have been determined by using yttria stabilized zirconia (YSZ) as a solid electrolyte in the following galvanic cells: The approach enables to verify in situ the establishment and maintenance of the /″-equilibrium, and to characterize it as a function of the phase composition of NKBA. The results can be expressed as follows:

Document Type: Research Article


Affiliations: 1: Max-Planck-Institut für Metallforschung, Pulvermetallurgisches Laboratorium, 70659 Stuttgart, Germany 2: The State Key Laboratory of High Performance Ceramics and Superfine Structure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Publication date: 2005-10-01

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