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Subsolidus Phase Relationships in the Ga2O3–Al2O3–TiO2 System

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Abstract:

Subsolidus phase relationships in the Ga2O3–Al2O3–TiO2 system at 1400°C were studied using X-ray diffraction. Phases present in the pseudoternary system include TiO2 (rutile), Ga2−2xAl2xO3 (x≤0.78 -gallia structure), Al2−2yGa2yO3 (y≤0.12 corundum structure), Ga2−2xAl2xTiO5 (0≤x≤1 pseudobrookite structure), and several -gallia rutile intergrowths that can be expressed as Ga4−4xAl4xTin−4O2n−2 (x≤0.3, 15≤n≤33). This study showed no evidence to confirm that aluminum substitution of gallium stabilizes the n=7 -gallia–rutile intergrowth as has been mentioned in previous work.

Document Type: Research Article

DOI: http://dx.doi.org/10.1111/j.1551-2916.2005.00484.x

Affiliations: School of Engineering, Alfred University, Alfred, New York 14802

Publication date: September 1, 2005

bsc/jace/2005/00000088/00000009/art00040
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