Effect of Mesoporous Silica Buffer Layer on the Orientation of MFI Zeolite Membranes
Abstract:Growth of MFI zeolite membranes on porous α-alumina substrates with and without precoated mesoporous silica buffer layer has been performed by in situ crystallization. A preferentially b-oriented MFI membrane can be prepared on a mesoporous silica-coated substrate. A membrane with a randomly oriented and eventually [h0h]-oriented top layer is obtained on an uncoated α-alumina substrate. The chemical properties of the substrate are suggested to have significant effects on the membrane orientation.
Document Type: Research Article
Affiliations: Ceramics Research Laboratory, Nagoya Institute of Technology, Tajimi, Gifu 507-0071, Japan
Publication date: 2005-08-01