Skip to main content

Microstructural Development on Firing Illite and Smectite Clays Compared with that in Kaolinite

Buy Article:

$48.00 plus tax (Refund Policy)

Abstract:

Thermal transformation of illite and smectite group clay minerals was studied using X-ray diffraction and transmission electron microscopy, and the results were compared with those of kaolinite. Differences were observed in the types and sizes of crystals formed at temperatures between 800° and 1400°C. Spinel-type phases were formed after 3 h at 1000°C in all three clays, but the morphology and composition of the spinel crystals varied. Mullite crystals reached greater sizes in the illite (>10 m needles) and smectite (>1 m) materials than in the kaolinite (0.5 m). Iron-rich crystals formed in the illite and smectite materials, and feldspars present as impurities in these clays, along with interlayer cations, resulted in large quantities of liquid being formed above 1000°C. Similar thermal breakdown and phase development schemes are proposed for all three materials, with the major differences observed ascribed to the presence or absence of interlayer cations, substitutional impurities, and accessory minerals. These results provide a basis for predicting phase development on firing a given clay mineral, if its characteristics and impurity levels are known.

Document Type: Research Article

DOI: http://dx.doi.org/10.1111/j.1551-2916.2005.00390.x

Affiliations: Department of Engineering Materials, University of Sheffield, Sheffield S1 3JD, U.K.

Publication date: August 1, 2005

bsc/jace/2005/00000088/00000008/art00040
dcterms_title,dcterms_description,pub_keyword
6
5
20
40
5

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more