Preparation and Photoluminescence of Partially Filled ZnO Microtubes Using Block Copolymers

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Partially filled ZnO microtubes were synthesized in large scale using block copolymers. The growth mechanism of this unique construction is proposed on the basis of adsorption of block copolymers on {0002} plane of wurtzite ZnO. The photoluminescence property of these unique ZnO microtubes is also studied using a Xe lamp as the excitation source at room temperature. Blue emission band at 425 nm is a much stronger ultraviolet emission band, which is due to laminar structure of ZnO microtubes.

Document Type: Research Article


Affiliations: State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China

Publication date: June 1, 2005

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