Thermoelectric Performance of Epitaxial Thin Films of Layered Cobalt Oxides Grown by Reactive Solid-Phase Epitaxy with Topotactic Ion-Exchange Methods

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Abstract:

This article reviews high-quality epitaxial film growth of layered cobalt oxides by reactive solid-phase epitaxy (R-SPE) with topotactic ion-exchange methods. Epitaxial film of Na0.8CoO2 was grown on a (0001)-oriented α-Al2O3 substrate by R-SPE using CoO film as the starting material. The Na0.8CoO2 epitaxial films were converted into high-quality epitaxial films of Sr0.32Na0.21CoO2 and [Ca2CoO3]xCoO2 by topotactic ion-exchange methods. The Sr0.32Na0.21CoO2 film exhibited better stability against moisture than that of the Na0.8CoO2 film, while it retained the good thermoelectric properties of Na0.8CoO2. The [Ca2CoO3]xCoO2 film exhibited a high electrical conductivity of 2.95 × 102 S/cm and a large Seebeck coefficient of +125 V/K at 300 K.

Document Type: Research Article

DOI: http://dx.doi.org/10.1111/j.1744-7402.2007.02145.x

Affiliations: Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan

Publication date: August 1, 2007

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