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Tetr--acetato-8O:O′-bis­[(3-hydroxy­pyridine-N)copper(II)]

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Abstract:

In the title dimeric complex, [Cu2(Ac)4(3-PyOH)2] or [Cu2(C2H3O2)4(C5H5NO)2] (Ac is acetate and PyOH is hydroxy­pyridine), each CuII atom exists in a square pyramidal coordination environment, defined by four different acetate O atoms and one 3-hydroxy­pyridine N atom. Two CuII atoms are bridged by four acetate groups, and the center of the dimer corresponds to a crystallographic center of symmetry, the Cu…Cu separation being 2.6598 (8) Å. These dimeric units are linked via O—H…O hydrogen bonds into a two-dimensional layer supramolecular network.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S1600536804021993

Publication date: October 1, 2004

bsc/aye/2004/00000060/00000010/art00023
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