Authors: Li, Xin-Hua; Chi, Xian-Xing
Source: Acta Crystallographica Section E, Volume 60, Number 9, September 2004 , pp. m1301-m1302(2)
Abstract:By reaction of cobalt(II) sulfate with 5-hydroxyisophthalic acid and 2,2′-bipyridine in a water-dimethylformamide solution, the title novel sulfate-anion-bridged inorganic-organic hybrid, [Co(C10H8N2)(H2O)2SO4]n, has been synthesized. Structural characterization of the complex shows that it displays a polymeric linear structure, formed by sulfate bridges between six-coordinate CoII ions that lie on twofold rotation axes. Hydrogen bonding between chains results in a two-dimensional framework stucture.
Document Type: Research article
Publication date: 2004-09-01