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catena-Poly­[[di­aqua(2,2′-bi­pyridine-2N,N′)­cobalt(II)]--sulfato]

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Abstract:

By reaction of cobalt(II) sulfate with 5-hydroxy­isophthalic acid and 2,2′-bi­pyridine in a water–di­methyl­form­amide solution, the title novel sulfate-anion-bridged inorganic–organic hybrid, [Co(C10H8N2)(H2O)2SO4]n, has been synthesized. Structural characterization of the complex shows that it displays a polymeric linear structure, formed by sulfate bridges between six-coordinate CoII ions that lie on twofold rotation axes. Hydrogen bonding between chains results in a two-dimensional framework stucture.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S1600536804019038

Publication date: September 1, 2004

bsc/aye/2004/00000060/00000009/art00043
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