catena-Poly­[[di­aqua(2,2′-bi­pyridine-κ²N,N′)­cobalt(II)]-μ-sulfato]

Authors: Li, Xin-Hua; Chi, Xian-Xing

Source: Acta Crystallographica Section E, Volume 60, Number 9, September 2004 , pp. m1301-m1302(2)

Publisher: Wiley-Blackwell

Abstract:

By reaction of cobalt(II) sulfate with 5-hydroxy­isophthalic acid and 2,2′-bi­pyridine in a water-di­methyl­form­amide solution, the title novel sulfate-anion-bridged inorganic-organic hybrid, [Co(C₁₀H₈N₂)(H₂O)₂SO₄]_n, has been synthesized. Structural characterization of the complex shows that it displays a polymeric linear structure, formed by sulfate bridges between six-coordinate Co^II ions that lie on twofold rotation axes. Hydrogen bonding between chains results in a two-dimensional framework stucture.

Document Type: Research article

DOI: http://dx.doi.org/10.1107/S1600536804019038

Publication date: 2004-09-01

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