[Bis(3-diphenylphosphinopropyl)phenylphosphine-³P,P,P]chloroplatinum(II) perchlorate: [PtCl(C₃₆H₃₇P₃)]ClO₄

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By this author: Klint S.T. ;&nbsp; Simonsen O. ;&nbsp; <a href="/search;jsessionid=3an5cmjgq7gng.alice?option2=author&value2=Andreasen+LV">Andreasen L.V. ;&nbsp; Bond A.D. ;&nbsp; Wernberg O.

Authors: Klint S.T.; Simonsen O.; Andreasen L.V.; Bond A.D.; Wernberg O.

Source: Acta Crystallographica Section E, Volume 60, Number 1, January 2004 , pp. m17-m19(3)

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Abstract:

The crystal structure of the title complex, [PtCl(C₃₆H₃₇P₃)]ClO₄, at 145 K contains the trimethylene-bridged triphosphine chelate ligand Ph₂P(CH₂)₃PPh(CH₂)₃PPh₂ coordinated in a tridentate manner to the Pt^II atom. The coordination geometry about Pt is distorted from square planar as a consequence of the geometrical constraints of the chelating ligand.

Document Type: Research article

DOI: http://dx.doi.org/10.1107/S160053680302720X

Publication date: 2004-01-01