Pseudosymmetry in a cyclopalladated compound
Abstract:The enantiomerically pure title complex, [SP‐4‐4]‐(R)‐[2‐(1‐aminoethyl)phenyl‐κ2 C 1,N]chlorido(quinoline‐κN)palladium(II) acetone hemisolvate, [Pd(C8H10N)Cl(C9H7N)]·0.5C3H6O, crystallizes with four molecules of the organopalladium complex and two molecules of acetone in the asymmetric unit. This corresponds to a discrete hydrogen‐bonded aggregate and to the content of the unit cell in the space group P1. Pronounced pseudo‐inversion symmetry relates pairs of these objects in the asymmetric unit.
Document Type: Research Article
Affiliations: Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
Publication date: August 15, 2012