Poly[[(μ2‐4,4′‐bipyridine)(μ3‐5‐isonicotinamidoisophthalato)cobalt(II)] trihydrate]

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In the title compound, {[Co(C14H8N2O5)(C10H8N2)]ยท3H2O} n , the CoII cation is five‐coordinated with a slightly distorted trigonal–bipyramidal geometry, and the 5‐isonicotinamidoisophthalate ligands link CoII atoms into a layered structure. These two‐dimensional arrays are further pillared by rod‐like 4,4′‐bipyridine ligands to give a three‐dimensional framework with pcu (primitive cubic) topology. The magnetic and adsorption properties of the title compound are also discussed.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270112030582

Affiliations: Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Department of Chemistry and Materials Science, Hengyang, Hunan 421008, People's Republic of China

Publication date: August 15, 2012

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