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(Acetylacetonato‐κ2O,O′)[1‐(4‐bromophenyl‐κC2)‐3‐methylimidazol‐2‐ylidene‐κC2]platinum(II)

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Abstract:

The title platinum(II) complex, [Pt(C10H8BrN2)(C5H7O2)], has a bidentate cyclometallated phenylimidazolylidene ligand and an acetylacetonate spectator ligand, which form a distorted square‐planar coordination environment around the PtII centre. In the solid state, the molecules are oriented in a parallel fashion by intermolecular hydrogen bonding and π–π and C—H...π interactions, while close Pt...Pt contacts are not observed. The structure is only the second example for this new class of compounds.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270112027783

Affiliations: Physikalische Organische Chemie, Technische Universit├Ąt Dresden, 01069 Dresden, Germany

Publication date: August 15, 2012

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