@article {Blanco:2012:0108-2701:o126,
	author = "Blanco, Maria Camila and Palma, Alirio and Cobo, Justo and Glidewell, Christopher",
	title = "Chain formation by disordered, but correlated, hydrogen bonds in icis/i-(2iRS/i,4iSR/i)-2-(thiophen-2-yl)-2,3,4,5-tetrahydro-1iH/i-1-benzazepin-4-ol and icis/i-(2iRS/i,4iSR/i)-2-(5-methylthiophen-2-yl)-2,3,4,5-tetrahydro-1iH/i-1-benzazepin-4-ol",
	journal = "Acta Crystallographica Section C",
	volume = "68",
	number = "3",
	year = "2012",
	abstract = "The closely related compounds <I>cis</I>-(2<I>RS</I>,4<I>SR</I>)-2-(thiophen-2-yl)-2,3,4,5-tetrahydro-1<I>H</I>-1-benzazepin-4-ol, C<SUB>14</SUB>H<SUB>15</SUB>NOS, (I), and <I>cis</I>-(2<I>RS</I>,4<I>SR)</I>-2-(5-methylthiophen-2-yl)-2,3,4,5-tetrahydro-1<I>H</I>-1-benzazepin-4-ol, C<SUB>15</SUB>H<SUB>17</SUB>NOS, (II), both crystallize with <I>Z</I>&#8242; = 2 in the space group <I>P</I>&#60;inlineGraphic alt="inline image" href="urn:x-wiley:01082701:AYCYF3011:AYC_yf3011_mu1" location="equation/AYC_yf3011_mu1.gif"/&#62;. In (I), the thienyl substituent in one of the two independent molecules is disordered over two sets of atomic sites having occupancies of 0.856&#8197;(2) and 0.144&#8197;(2). In both compounds, the two independent hydroxy O atoms are both within 2.8&#8197;&#197; of the hydroxy O atoms of two neighbouring molecules, and all of the hydroxy H atoms are disordered, each over two sites. The resulting O&#8212;H...O hydrogen bonds generate two similar but distinct <I>C</I><SUB>4</SUB><SUP>4</SUP>(8) chains, depending upon which hydroxy H-atom sites are occupied or vacant, with full correlation of the hydroxy H-atom occupancies within each chain. Comparisons are made with the supramolecular assembly in some related compounds.",
	pages = "o126-o130",
	url = "http://www.ingentaconnect.com/content/bsc/ayc/2012/00000068/00000003/art00020",
	doi = "doi:10.1107/S0108270112003988"
}