Skip to main content

Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds

Buy Article:

$51.00 plus tax (Refund Policy)

Abstract:

Diammonium carbonate hydrogen peroxide monosolvate, 2NH4 +·CO3 2−·H2O2, (I), and dicaesium carbonate hydrogen peroxide trisolvate, 2Cs+·CO3 2−·3H2O2, (II), were crystallized from 98% hydrogen peroxide. In (I), the carbonate anions and peroxide solvent molecules are arranged on twofold axes. The peroxide molecules act as donors in only two hydrogen bonds with carbonate groups, forming chains along the a and c axes. In the structure of (II), there are three independent Cs+ ions, two of them residing on twofold axes, as are two of the four peroxide molecules, one of which is disordered. Both structures comprise complicated three‐dimensional hydrogen‐bonded networks.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270112006701

Publication date: March 15, 2012

bsc/ayc/2012/00000068/00000003/art00004
dcterms_title,dcterms_description,pub_keyword
6
5
20
40
5

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more