Skip to main content

Tetraaquabis[5‐(3‐pyridyl‐κ

Buy Article:

$43.00 plus tax (Refund Policy)

The title compound, [Zn(C9H7N3)2(H2O)4](CF3O3S)2, contains an octahedral [ZnL 2(H2O)4]2+ cationic complex with trans geometry (Zn site symmetry ), and each 5‐(3‐pyridyl)pyrimidine (L) ligand is coordinated in a monodentate fashion through the pyridine N atom. In the extended structure, these complexes, with both hydrogen‐bond acceptor (pyrimidine) and donor (H2O) functions, are linked to each other by intermolecular water–pyrimidine O—H...N hydrogen‐bonding interactions, resulting in a double chain along the crystallographic a axis. The trifluoromethanesulfonate anions are integrated into the chains via O—H...O hydrogen bonds between the coordinated water and sulfonate O atoms. These double chains are associated into a novel three‐dimensional network through interchain water–pyrimidine O—H...N hydrogen bonds. The asymmetric ligand plays an important role in constructing this unusual supramolecular structure.
No References
No Citations
No Supplementary Data
No Data/Media
No Metrics

Document Type: Research Article

Affiliations: College of Pharmacy, Binzhou Medical University, Yantai 264003, People's Republic of China

Publication date: 2011-10-15

  • Access Key
  • Free content
  • Partial Free content
  • New content
  • Open access content
  • Partial Open access content
  • Subscribed content
  • Partial Subscribed content
  • Free trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more