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A novel one-dimensional zigzag coordination polymer of copper(II) with di­methyl­glyoxime

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A novel metal-organic based polymeric complex, namely catena-poly­[[bis(4-di­methyl­glyoximato)­bis(2-di­methyl­gly­oxi­mato)­bis­(di­methyl­glyoxime)­tetracopper(II)] diperchlorate dihydrate], {[Cu4(dmg)2(Hdmg)2(H2dmg)2](ClO4)2·2H2O} (H2dmg is di­methyl­glyoxime, C2H8N2O2), has been synthesized and characterized by single-crystal X-ray diffraction methods. The complex is a one-dimensional zigzag chain coordination polymer, in which the tetranuclear repeat unit is a centrosymmetric Cu4 moiety coordinated to di­methyl­glyoxime ligands only. These units are linked by double Cu—O—Cu bridges in a centrosymmetric rectangular ­junction.
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Document Type: Research Article

Publication date: 2004-10-01

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