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Poly­[[di­aqua­cobalt(II)]-di--4-cyano­benzoato-4O:O′]

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Abstract:

The title compound, [Co(C8H4NO2)2(H2O)2]n, which was obtained by the reaction of CoCl2·6H2O with 4-cyano­benzoic acid, is the first two-dimensional 4-cyano­benzoate cobalt(II) polymer. The Co atom lies on a centre of symmetry and its coordination polyhedron is a slightly distorted octahedron, defined by two water and four carboxyl­ate O atoms. The 4-cyano­benzoate (cba) anion is bridging in a syn-skew coordination mode, which ensures a two-dimensional architecture with the building block Co4(cba)4.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104021766

Publication date: October 1, 2004

bsc/ayc/2004/00000060/00000010/art00026
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