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A two-dimensional manganese(II) coordination polymer: poly­[[di­aqua­manganese(II)]--4,4-bi­pyridine-2N:N′--(p-phenyl­ene­dioxy­diacetato)-2O:O′]

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Abstract:

In the title two-dimensional coordination polymer, [Mn(1,4-BDOA)(4,4-bipy)(H2O)2]n [1,4-BDOA2− is the p-phenyl­ene­dioxy­di­acetate dianion (C10H8O6) and 4,4-bipy is 4,4-bi­pyridine (C10H8N2)], each MnII atom displays octahedral coordination by two O atoms of the 1,4-BDOA2− groups, two N atoms of the 4,4-bipy ligands and two solvent water mol­ecules. The MnII atom, 4,4-bipy ligand and 1,4-BDOA2− group occupy different inversion centres. Adjacent MnII atoms are bridged by 1,4-BDOA2− groups and 4,4-bipy ligands, forming a two-dimensional network with Mn…Mn separations of 11.592 (2) and 11.699 (2) Å. Hydro­gen bonds from a water O—H group link the layers in the third dimension.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104021481

Publication date: October 1, 2004

bsc/ayc/2004/00000060/00000010/art00025
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