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A two-dimensional manganese(II) coordination polymer: poly­[[di­aqua­manganese(II)]--4,4-bi­pyridine-2N:N′--(p-phenyl­ene­dioxy­diacetato)-2O:O′]

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In the title two-dimensional coordination polymer, [Mn(1,4-BDOA)(4,4-bipy)(H2O)2]n [1,4-BDOA2− is the p-phenyl­ene­dioxy­di­acetate dianion (C10H8O6) and 4,4-bipy is 4,4-bi­pyridine (C10H8N2)], each MnII atom displays octahedral coordination by two O atoms of the 1,4-BDOA2− groups, two N atoms of the 4,4-bipy ligands and two solvent water mol­ecules. The MnII atom, 4,4-bipy ligand and 1,4-BDOA2− group occupy different inversion centres. Adjacent MnII atoms are bridged by 1,4-BDOA2− groups and 4,4-bipy ligands, forming a two-dimensional network with Mn…Mn separations of 11.592 (2) and 11.699 (2) Å. Hydro­gen bonds from a water O—H group link the layers in the third dimension.
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Document Type: Research Article

Publication date: 01 October 2004

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