Polysulfonylamines. CLXXI. [Di(methanesulfonyl)amido-N]bis(2-picoline-N)copper(I)
Abstract:The title compound, [Cu(C2H6NO4S2)(C6H7N)2], consists of monomeric molecules in which the Cu atom displays planar but irregular coordination by three N-atom donors; Cu—N = 2.1054 (12) (amide N), 1.9514 (12) and 1.9589 (12) Å, and N—Cu—N = 141.24 (5), 111.54 (5) and 107.20 (5)°. Intramolecular Cu…O contacts are observed. The packing involves (interconnected) layer formation via C—H…O interactions in two directions, three hydrogen bonds combining to form layers parallel to (101) and five to form layers parallel to (10 ).
Document Type: Research Article
Publication date: October 1, 2004