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Poly­[manganese(II)-2-benzidine-2N:N′-3-bi­phenyl-2,2′-di­carboxylato-4O:O′,O′′:O′′′]

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Abstract:

The title compound, [Mn(C14H8O4)(C12H12N2)]n, with a novel three-dimensional framework, has been prepared by a hydro­thermal reaction at 433 K. Each Mn atom lies on a twofold axis in a slightly distorted octahedral geometry, coordinated by two N atoms from two benzidine ligands and four O atoms from three symmetry-related biphenyl-2,2′-dicarboxylate (bpdc) ligands. The benzidine ligands lie about inversion centres and the bpdc ligands about twofold axes. Each bpdc ligand is bonded to three Mn ions to form a continuous chain of metal ions. The bpdc ligands are accommodated in a series of distorted holes resembling hexagonal prisms.

Document Type: Research Article

DOI: https://doi.org/10.1107/S0108270104020050

Publication date: 2004-10-01

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