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A new binding mode for thio­sulfate in six-coordinate poly­[[(1,10-phenanthroline-2N,N′)­cadmium(II)]--thio­sulfato]

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In the novel title six-coordinate cadmium complex, [Cd(S2O3)(C12H8N2)]n, the anion binds to three different six-coordinate cationic centres through all four external atoms, an unprecedented coordination mode for thio­sulfate metal-organic complexes. This connectivity leads to strongly linked dimers, connected to form interleaved double chains, which in turn interact through remarkably short – bonds between their phenanthroline groups.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104019638

Publication date: October 1, 2004

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