Tetrakis(2,2′-bipyridine-2N,N′)­tetrakis(-salicyl­ato-3O,O′:O′′)-quadro-tetrazinc(II) decahydrate

$48.00 plus tax (Refund Policy)

Download / Buy Article:

Abstract:

The title compound, [Zn4(C7H4O3)4(C10H8N2)4]·10H2O, crystallizes as a centrosymmetric tetranuclear cyclic complex containing four ZnII atoms bridged by four carboxyl­ate groups from salicyl­ate ligands, with a synanti configuration. Each ZnII atom has a distorted trigonal–bipyramidal coordination geometry, formed by two N atoms of a 2,2′-bipyridine ligand and three O atoms from two salicyl­ate ligands. The complex is stabilized by intramolecular – interactions between pairs of bi­pyridine rings and a 16-membered gear-wheel-shaped cyclic framework. The hydrogen-bonding network is formed via the water mol­ecules.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S010827010401950X

Publication date: October 1, 2004

Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more