In the title complex, [Ag(NO3)(C14H14N4S4)]n, the AgI atom lies on a twofold axis and shows a distorted tetrahedral coordination, comprised of two N-atom donors from two thiadiazole groups of separate ligands and two O-atom donors from one nitrate ligand. Each bis(thioether) ligand also lies on a twofold axis and bridges two adjacent Ag atoms to form an infinite chain along the c axis, with an Ag…Ag separation of 11.462 (4) Å. Adjacent one-dimensional chains are further linked into double-chain motifs through weak Ag…S and – stacking interactions.
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Document Type: Research Article
Publication date: 2004-10-01