catena-Poly­[[(nitrato-2O,O′)silver(I)]--2,2′-[1,4-phenyl­enebis­(methyl­ene­thio)]­bis(5-methyl-1,3,4-thia­diazo­le)-2N3:N3′]

Author: Zheng, Yan

Source: Acta Crystallographica Section C, Volume 60, Number 10, October 2004 , pp. m471-m472(2)

Publisher: Wiley-Blackwell

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Abstract:

In the title complex, [Ag(NO3)(C14H14N4S4)]n, the AgI atom lies on a twofold axis and shows a distorted tetrahedral coordination, comprised of two N-atom donors from two thia­diazole groups of separate ligands and two O-atom donors from one nitrate ligand. Each bis­(thio­ether) ligand also lies on a twofold axis and bridges two adjacent Ag atoms to form an infinite chain along the c axis, with an Ag…Ag separation of 11.462 (4) Å. Adjacent one-dimensional chains are further linked into double-chain motifs through weak Ag…S and – stacking interactions.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104019183

Publication date: October 1, 2004

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