Skip to main content

catena-Poly­[[(nitrato-2O,O′)silver(I)]--2,2′-[1,4-phenyl­enebis­(methyl­ene­thio)]­bis(5-methyl-1,3,4-thia­diazo­le)-2N3:N3′]

Buy Article:

$51.00 plus tax (Refund Policy)

Abstract:

In the title complex, [Ag(NO3)(C14H14N4S4)]n, the AgI atom lies on a twofold axis and shows a distorted tetrahedral coordination, comprised of two N-atom donors from two thia­diazole groups of separate ligands and two O-atom donors from one nitrate ligand. Each bis­(thio­ether) ligand also lies on a twofold axis and bridges two adjacent Ag atoms to form an infinite chain along the c axis, with an Ag…Ag separation of 11.462 (4) Å. Adjacent one-dimensional chains are further linked into double-chain motifs through weak Ag…S and – stacking interactions.

Document Type: Research Article

DOI: https://doi.org/10.1107/S0108270104019183

Publication date: 2004-10-01

  • Access Key
  • Free ContentFree content
  • Partial Free ContentPartial Free content
  • New ContentNew content
  • Open Access ContentOpen access content
  • Partial Open Access ContentPartial Open access content
  • Subscribed ContentSubscribed content
  • Partial Subscribed ContentPartial Subscribed content
  • Free Trial ContentFree trial content
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more