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Transition metal complexes with pyrazole-based ligands. XIX. Di­aqua­bis(3,5-di­methyl-1H-pyrazole-1-carbox­amidine-2N,N′)­metal(II) ­dinitrate, with metal = Co and Ni

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Abstract:

The two title isostructural and isomorphous complexes, [M(C6H10N4)2(H2O)2](NO3)2 (M is Co or Ni), contain the transition metal in a distorted octahedral geometry, coordinated by four N atoms of two neutral bidentate organic ligands in the equatorial plane and two water O atoms mol­ecules in the axial positions. The cation is centrosymmetric, with the transition metal located on an inversion centre. The structures are stabilized by a three-dimensional network of hydrogen bonding.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104017433

Publication date: October 1, 2004

bsc/ayc/2004/00000060/00000010/art00002
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