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4,4,6,6-Tetra­chloro-2,2-(propyl­ene­dioxy­di-o-phenyl­enedi­imino)-25,45,65-cyclotriphosphazene

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Abstract:

The title compound, C15H16Cl4N5O2P3, is a cyclo­phosphazenic lariat (PNP-pivot) ether with a spiro-cyclic 12-membered macrocyclic ligand containing two ether O and two N atoms; the phosphazene ring is nearly planar. In the macrocyclic ring, there is a four-center (trifurcate) N—H…O/N—H…N hydrogen bond. The relative inner-hole size of the macrocycle is estimated as approximately 0.95 Å.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104006894

Publication date: June 1, 2004

bsc/ayc/2004/00000060/00000006/art00026
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