catena-Poly­[[aqua(2,2′-bi­pyridine-2N,N′)­manganese(II)]--terephthalato-3O,O′:O′′]

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Abstract:

The title complex, [Mn(C8H4O4)(C10H8N2)(H2O)]n, takes the form of a zigzag chain, with the terephthalate dianion (tp) acting as a tridentate ligand. The MnII center is surrounded by two tp ligands, one water mol­ecule and one 2,2′-bi­pyridine (bipy) ligand and exhibits a severely distorted octahedral coordination environment, with cis angles ranging from 57.31 (8) to 123.97 (11)°. The complete solid-state structure can be described as a three-dimensional supramolecular framework stabilized by hydrogen-bonding interactions involving the coordinated water mol­ecule and the carboxy O atoms of the tp ligands, and by – stacking interactions involving the bipy rings and the benzene ring of the tp ligand.

Document Type: Research Article

DOI: http://dx.doi.org/10.1107/S0108270104007565

Publication date: June 1, 2004

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